Heat-constrained modelling of calcium sulphate reduction
نویسندگان
چکیده
A two-dimensional finite difference model has been developed to describe the reduction of kilogram quantities dehydrated phosphogypsum. The model's scope limited focus on heat transfer and reactions that occur within a mass material contained in vessel inside furnace rather than also including effects vessel. Changes properties (k, p, Cp) are incorporated as composition changes chemical progress. is validated against experimental data, with samples heated iooo°C at 3°C min-1 while purging nitrogen gas. sensitivity analysis predictions pre-exponential factor reaction rate constant main thermal conductivity powder bed indicated that, envisaged process conditions, behaviour system depends much more reaction. demonstrated significant increase accuracy when was modelled linearly temperature compared assuming value.
منابع مشابه
Modelling of Bacterial Sulphate Reduction in Anaerobic Ponds: Kinetic Investigations
The aim of the study was first to develop a simple and practical model of anaerobic digestion including sulphate-reduction in anaerobic ponds. The basic microbiology of our model consists of three steps, namely, acidogenesis, methanogenesis, and sulphate reduction. This model includes multiple reaction stoichiometry and substrate utilization kinetics. The second aim was to determine some kineti...
متن کاملModelling of calcium sulphate solubility in concentrated multi-component sulphate solutions
The chemistry of several calcium sulphate systems was successfully modelled in multi-component acid-containing sulphate solutions using he mixed solvent electrolyte (MSE) model for calculating the mean activity coefficients of the electrolyte species. The modelling involved the tting of binary mean activity, heat capacity and solubility data, as well as ternary solubility data. The developed mo...
متن کاملPhotosynthetic Sulphate Reduction
Plants assimilate inorganic sulphate for the bio synthesis of sulphur containing compounds. The enzymes required for reduction are found pre dominantly in the plastids which provide the necessary energy and the reductants. Sulphate re duction like nitrate or carbon dioxide assimilation is endergonic; for comparison, N 0 3 reduction to ammonia requires +347 kJ mol1 and C 0 2 re duction +478 ...
متن کاملChemical Modelling of Calcium Sulphate Phase Equilibria in Multicomponent Electrolyte Solutions
A new database was developed to successfully model the solid and aqueous phase equilibria in a number of hydrometallurgical processes using the Mixed Solvent Electrolyte (MSE) model of the OLI Systems software. In order to validate the predictability of the model developed, a number of experimental measurements were conducted in multicomponent solutions containing NiSO4, H2SO4, MnSO4, HCl, etc....
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of The South African Institute of Mining and Metallurgy
سال: 2022
ISSN: ['2411-9717', '0038-223X']
DOI: https://doi.org/10.17159/2411-9717/1530/2022